IAEA-S-1 参考物质及V-CDTS 同位素标准的32S/34S绝对比值     

丁悌平  白瑞梅  李延河  万德芳  邹晓秋  张青莲 《地球学报》1997,18(Z1):293-296

采用高纯S同位素物质和SF6的分析方法对IAEA-S-1参考物质及V-CDT S同位素标准的32S/34S绝对比值进行了实验标定，V-CDT的32S/34S比值为22.6496±0.060，IAEA-S-1的32S/34S比值为22.6564±0.0060.  相似文献   

Evidence of early generation of liquid hydrocarbon from suberinite as visible under the microscope   总被引：1，自引：0，他引：1  

Wan Hasiah Abdullah   《Organic Geochemistry》1997,27(7-8)

The early generation of liquid hydrocarbons from suberinite can be clearly observed under the microscope. The generation of this oil-like material, mainly in the form of exsudatinite, from the maceral suberinite occurs at a maturity level of about 0.4% vitrinite reflectance. Hydrocarbons appear to be naturally expelled from coal initially through sweating and agglomeration of suberinite which subsequently forms exsudatinite. It is suggested that extensive expulsion of exsudatinite causes cracks to develop in vitrinite whereas limited expulsion of exsudatinite will only impregnate the vitrinite matrix. If cracks are formed, it is possible they could progressively develop to form an exsudatinite-crack network. The formation of such a network is believed to represent an effective way of hydrocarbon expulsion from coal source rocks.  相似文献   

现代沉积的²¹⁰Pb计年   总被引：74，自引：10，他引：74       下载免费PDF全文

万国江 《第四纪研究》1997,17(3):230-239

²¹⁰Pb具有百年时间尺度沉积计年的重要价值。²¹⁰Pb_ex计年假设：沉积物是封闭系统；进入水体的²¹⁰Pb能有效地转移到沉积物中并不发生沉积后迁移；非过剩²¹⁰Pb与其母体²²⁶Ra保持平衡。²¹⁰Pb_ex计年可用稳定输入通量-稳定沉积物堆积速率模式、常量初始浓度模式或恒定补给速率模式。沉积物柱芯必须保持原态并以0．5～1cm间隔分截；用相应层节²²⁶Ra校正。沉积物表层混合作用及²²²Rn的丢失可能导致顶部²¹⁰Pb_ex异常。季节性缺氧湖泊沉积物顶部可能存在²¹⁰Pb及²¹⁰Po的再迁移。²¹⁰Pb与¹³⁷Cs两种计年方法原理上具有根本差别。²¹⁰Pb，¹³⁷Cs与沉积纹理方法对比是准确计年的重要保证。  相似文献   

湖泊沉积物-水界面营养元素的生物地球化学作用和环境效应　Ⅰ.界面氮循环及其环境效应   总被引：7，自引：0，他引：7  

吴丰昌  万国江  黄荣贵 《矿物学报》1996,(4)

发生在沉积物-水界面的剧烈生物地球化学作用对沉积物和上覆水体具重要的环境效应，然而此方面研究很少。本文通过云贵高原四个湖泊湖水和孔隙水NH和NO剖面，沉积物柱芯不同结合态氮含量剖面分布，界面扩散通量，影响氮循环的因素及它们季节性变化规律等的对比研究，初步揭示了湖泊沉积物一水界面的氮循环及其环境效应。  相似文献   

Behaviours of REE and Other Trace Elements During Pedological Weathering-Evidence from Chemical Leaching of Loess and Palaeosol from the Luochuan Section in Central China     

Chen Jun  Wan Hongtao  Department of Earth Sciences  Nanjing University  Nanjing  Jiangsuand Lu HuayuKey Lab. of Loess  Quaternary Geology  Chinese Academy of Sciences  Xi an  Shaanxi Liu Xinzhu 《《地质学报》英文版》1996,70(3):290-302

The chemical leaching method is used for a systematic analysis of distribution characteristics of acid-soluble and acid-insoluble REE and other trace elements from the Luochuan loess deposits. The study shows that the acid-insoluble phase in loess and palaeosol is a stable component of old aeolian dusts and is characteristic of the provenance; the acid-soluble phase is the unstable component in the weathering pedogenic process and reflects rock-forming features after accumulation of aeolian dusts. The acid-insoluble REE and acid-soluble Sr and Pb can be used as geochemical indicators respectively to trace the provenance characteristics and the weathering pedogenic process.  相似文献   

The Influence of Element Diffusion at the Sediment—Water Interface on the Basic Chemical Composition of Overlying Water Mass in Lake Lugu,China     

吴丰昌  万国江等 《中国地球化学学报》1996,15(3):285-288

Little work has been done on the influence of seiments on the basic chemical composition of overlying water mass.This paper deals with the vertical profile of the basic constituents such as Ca^ ,K^ ,Na^ ,and HCO3^-,as well as of pH in the overlying water mass and sediment porewater of Lake Lugu-a semi-closed,deep lake in Yunnan Province.The reand sediment porewater of Lake Lugu- a semi-closed,deep lake in Yunnan Province.The results revealed that those basic constituents may diffuse and transport from bottom sediments to overlying water mass through porewater.In the paper are also quantitatively evaluated the diffusive fluxes and the extent of their influence on overlying water mass,indicating that the lake sediment-water interface diffusion plays an important role in controlling the basic chemical composition of water in the whole lake.  相似文献   

低温条件下有机酸对铁、铜的淋滤实验研究     

张海祥  王玉荣  梅厚钧 《矿床地质》1997,16(1):86-92

水／岩作用实验研究表明，在低温条件下柠檬酸、草酸和酒石酸对岩石中的铁、铜都有很高的淋滤率。这表明，在表生地质作用过程中有机酸对成矿元素有很强的活化能力。实验研究同时发现，有机酸对成矿元素的活化能力受其分解温度的限制，由于大部分有机酸的分解温度都在２５０℃以下，因而有机酸对成矿元素的活化仅限于低温条件。本次研究还显示，判断一种岩石能否成为矿源层，不能简单的以其中成矿元素的含量高低作为标准，其中更关键的因素是元素在岩石中的存在形式，如果成矿元素在岩石中难以活化的形式存在，那么含量再高也无法提供成矿物质  相似文献   

山东招远北截金矿床地质特征及深部成矿预测   总被引：1，自引：1，他引：1  

颜丹平  万天丰  栾久春 《矿床地质》1997,16(4):365-375

对北截金矿的矿床与矿体地质构造及成矿模式和构造应力场的综合研究表明，北截金矿主要是受ＮＥ向的灵山沟－北截断裂控制，其储矿构造部位与与断裂带小角度斜交的ＮＮＥ向张剪性断裂，矿体主要分布于其中的２号矿带之中，矿体之间呈右行斜列为ＳＷ深部发展；百区内的ＮＷＷ向断裂为成矿后断裂，对矿体有较小的破坏作用；对矿区内Ａｕ、Ａｇ、Ａｓ、Ｍｏ、Ｓｂ、Ｂｉ进行的微量元素原生晕及Ａｇ／Ａｕ、Ａｓ／Ｍｏ与Ｓｂ／Ｂｉ比值分  相似文献   

Screening Effect of the Diffusive Boundary Layer in Sediments of Lake Aha in the Suburbs of Guiyang City,Guizhou Province   总被引：6，自引：0，他引：6  

万国江  万曦等 《中国地球化学学报》1997,16(4):347-352

The redox cycle of iron and manganese is a major geochemica process at the boundary layers of lake sediments.Lake Aha,which lies in the suburbs of Guiyang City,Guizhou Province,China,is a medium-sized artificial reservoir with seasonally anoxic hypolimnion,Long-term sedimentary accumulation of iron and manganese resulted in their enrichment in the upper sediments,In the anoxic season,Fe^2 and Mn^2 ,formed by diological oxidation,would diffuse up to overlying waters from sediments.However,the concentration of oxidation,would diffuse up to overlying waters from sediments,However,the concentration of Fe^2 increased later and decreased earlier than that of Mn^2 .Generally,sulfate reduction occurred at 6 cm below the sediment-water interface.Whereas,in the anoxic season.the reduction reached upper sediments,inhibiting the release of Fe^2 ,The Fe concentration of anoxic water is quickly decreased from high to low as a result of reduction of the suplhur system.  相似文献   

Paleocollapse structure as a passageway for groundwater flow and contaminant transport   总被引：1，自引：0，他引：1  

Wan Fang Zhou 《Environmental Geology》1997,32(4):251-257

 Paleocollapse structure is a rock collapse, resulting from the failure in the geological history of the bedrock overlying karstified limestone. Depending on the present hydrogeological conditions within the area of paleocollapse and the internal properties of these structures, they can provide a means to facilitate groundwater flow and contaminant transport. Inactive paleocollapse structures can be reactivated by human activities such as dam construction, mining underground minerals, pumping groundwater, and development of landfills. They can also be reactivated by natural events such as earthquakes and neotectonic movements. In the mines of northern China, sudden inflow of karst water from Ordovician limestone into drifts and mining stopes through paleocollapse structures has caused significant economic loss. Water pumping tests and accompanied dye traces are effective approaches of locating water-conducting paleocollapse structures. Grouting is probably the best means of preventing them from becoming geohazards. Received: 26 November 1996 · Accepted: 17 June 1997  相似文献